Ahh this can be a somewhat subjective question. One can experience different moods whilst driving and so it follows, the proper tune for the mood must be selected.
If it is to be a tune that evokes what I like to call the "Jeckyll to Hyde syndrome", one that you almost involuntarily drop the hammer at the stroke of the very first chord, I'd have to say it is ZZ Top's "Just got paid today". Second choice would have to be George Thorogood's "Gear Jammer". 100's more come to mind but those are my top choices
Just thought of another one....The Bottle Rocket's "Radar Gun". If you haven't heard this one you owe it to yourself to "youtube" it
Speaking of youtube, I just found one that strikes a familiar nerve. Check out Audio Slave's "Show me how to live" video.