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Everything You Wanted to Know about Oil!

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Old 04-17-2009, 08:50 AM
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Default Everything You Wanted to Know about Oil!

I found this very informative post about oil composition, viscosity, grades, weights, etc. on chrysler300C forum. It was a repost from a Ferrari forum. It is very long, but well worth the read.

Thickness has the same meaning as viscosity. Viscosity is a measure of the resistance of a fluid (liquid or gas) to flow. Fluids with high viscosity, such as molasses, flow more slowly than those with low viscosity, such as water. The greatest confusion is because of the way motor oils are labeled. It is an old system and is confusing to many people. I know the person is confused when they say that a 0W-30 oil is too thin for their engine because the old manual says to use 10W-30.

More confusion occurs because people think in terms of the oil thinning when it gets hot. They think this thinning with heat is the problem with motor oil. It would be more correct to think that oil thickens when it cools to room temperature and THIS is the problem. It is said that 90% of engine wear occurs at startup. If we are interested in engine longevity then we should concentrate our attention at reducing engine wear at startup.

Oils are chosen by the manufacturer to give the right thickness at the normal operating temperature of the engine. I will say this average oil temperature is 212 F, the boiling point of water. On the track that temperature is up to 302F. It is important to realize that these are two different operating environments and require different oils.

One thing that is no longer important is the ambient temperature. Older automotive owner manuals often recommended one oil for the summer and another for the winter. This is still necessary for air cooled engines but is no longer a consideration in pressurized water cooled engines. These engine blocks are kept at around 212 F all year round.

The viscosity of oil varies with its temperature. A “30” weight oil has a viscosity of 3 at 302 F ( 150 C ) and thickens to 10 at 212 F ( 100 C ). It further thickens to a viscosity of 100 at 104 F ( 40 C ) and is too thick to measure at the freezing point of 32 F ( 0 C ).

The automotive designers usually call for their engines to run at 212 F oil and water temperature with an oil thickness of 10. This is the viscosity of the oil, not the weight as labeled on the oil can. The engine is designed to run at 212 F at all external temperatures from Alaska to Florida. In a perfect world the oil thickness would be 10 at all times and all temperatures.

If the thickness of oil was 10 when you got in your car in the morning and 10 while driving it would be perfect. You would not have to warm up your engine. You could just get in the car and step on the gas. There would be little wear and tear on you engine, almost none.

The night before when you drove home from work the car was up the the correct operating temperature and the oil was the correct thickness, 10. Over night the engine cooled to room temperature and the oil thickened. It is 75 F in the morning now. The oil thickness is now around 150. It is too thick to lubricate an engine designed to run with an oil having a thickness of 10.

It is time to introduce the concept of lubrication. Most believe that pressure = lubrication. This is false. Flow = lubrication. If pressure was the thing that somehow lubricated your engine then we would all be using 90 weight oil. Lubrication is used to separate moving parts, to keep them from touching. There is a one to one relationship between flow and separation. If you double the flow you will double the separation pressure in a bearing. The pressure at the bearing entrance is irrelevant.

In fact the relationship between pressure and flow is in opposition. If you change your oil to a thicker formula the pressure will go up. It goes up because the resistance to flow is greater and in fact the flow must go down in order for the pressure to go up. They are inversely related. Conversely if you choose a thinner oil then the pressure will go down. This can only occur if the flow has increased.

It seems then that we should all be using the thinnest oil money can buy. This is partly true. More pressure is not better, it can only result from the impedance of oil flow. Remember that oil flow is the only thing that does the lubricating.

High flow does more than lubricate. It is one of the things used to cool the hottest parts of your engine, the pistons, valve areas and bearings. This cooling effect is as important as lubrication in your engine. If your engine is running hot use a thinner oil. The flow will increase and so will the cooling.

Ferrari recommends Helix Ultra Racing 10W-60 “for hot climate conditions racing type driving on tracks”. Note that they now realize the difference between the daily urban driver like me and the very different racing situation. These are widely different circumstances. I want to emphasize that they only want you to use this oil while racing in “hot climate conditions”. If you are racing in Watkins Glen up north use the 5W-40. If you are racing in Sebring in the middle of the Florida summer use the 10W-60. Around town in any climate, use the 0W-40.

It is time to dispel the notion that 0W-30 oil is too thin when our manual calls for 10W-30. A 0W-30 is always the better choice, always. The 0W-30 is not thinner. It is the same thickness as the 10W-30 at operating temperatures. The difference is when you turn your engine off for the night. Both oils thicken over the evening and night. They both had a thickness, a viscosity of 10 when you got home and turned your engine off. That was the perfect thickness for engine operation. As cooling occurs and you wake up ready to go back to work the next day the oils have gotten too thick for your engine to lubricate properly. It is 75 F outside this morning. One oil thickened to a viscosity of say 90. The other thickened to a viscosity of 40. Both are too thick in the morning at startup. But 40 is better than 90. Your engine wants the oil to have a thickness of 10 to work properly. You are better off starting with the viscosity of 40 than the honey-like oil with a viscosity of 90.

I repeat: More confusion occurs because people think in terms of the oil thinning when it gets hot. They think this thinning with heat is the problem with motor oil. It would be more correct to think that oil thickens when it cools to room temperature and THIS is the problem. In fact this is the problem.

A 0W-30 weight oil is not thinner than a 10W-30 oil. They both have the same thickness at operating temperature. The 0W-30 simply does not get as thick on cooling as the 10W-30. Both are still way to thick to lubricate an engine at startup.

The multigrade oils 0W-30 and 10W-30 also have a thickness of 10 at 212 F.
The difference is at 75 F, your startup temperature in the morning.

Oil type... Thickness at 75 F...Thickness at 212 F

Straight 30...... 250......................10
10W-30............100......................10
0W-30..............40 ......................10
Straight 10........30....................... 6

Now you can see that the difference between the desired thickness your engine requires ( = 10 ) is closest to the 0W-30 oil at startup. It is still too thick for normal operation. But it does not have far to go before it warms up and thins to the correct viscosity. Remember that most engine wear occurs at startup when the oil is too thick to lubricate properly. It cannot flow and therefore cannot lubricate. Most of the thick oil at startup actually goes through the bypass valve back to the engine oil sump and not into your engine oil ways. This is especially true when you really step on that gas pedal. You really need more lubrication and you actually get less.

Note that a straight 10 weight oil is also too thick for your engine at startup. It has a thickness of 30. Yet at operating temperatures it is too thin having a thickness of 6. It needs to be around 10. The oil companies have added viscosity index improvers or VI to oils to solve this dilemma. They take a mineral based oil and add VI improvers so that it does not thin as as much when it gets hotter. Now instead of only having a thickness of 6 when hot it has a thickness of 10, just as we need.

The penalty is the startup thickness also goes up to 100. This is better than being up at 250 as a straight 30 weight oil though. Oil with a startup thickness of 100 that becomes the appropriate thickness of 10 when fully warmed up is called a 10W-30 weight motor oil. This is NOT as thick as a straight 30 weight oil at startup and it is NOT as thin as a straight 10 weight oil at full operating temperature.

The downside of a mineral based multigrade oil is that this VI additive wears out over time and you end up with the original straight 10 weight oil. It will go back to being too thin when hot. It will have a thickness of 6 instead of 10. This may be why Porsche (according to some people) does not want a 0W-30 but rather a 10W-30. If the VI wears out the 0W-30 will ultimately be thinner, a straight 0 weight oil. When the VI is used up in the 10W-30 oil it too is thinner. It goes back to a straight 10 weight oil. They are both still too thick at startup, both of them. The straight 0 weight oil, a 5 weight oil and a 10 weight oil are all too thick at startup.

This is just theory however. With normal oil change intervals the VI improver will not wear out and so the problem does not really exist. In fact, oils do thin a little with use. This is partly from dilution with blow by gasoline and partly from VI improvers being used up. What is more interesting is that with further use motor oils actually thicken and this is much worse than the minimal thinning that may have occurred earlier.

Synthetic oils are a whole different story. There is no VI improver added so there is nothing to wear out. The actual oil molecules never wear out. You could almost use the same oil forever. The problem is that there are other additives and they do get used up. I suppose if there was a good way to keep oil clean you could just add a can of additives every 6 months and just change the filter, never changing the oil. When the additives wear out in a synthetic oil it still has the same viscosity. It will not thin as a mineral oil.

The reality is that motor oils do not need to be changed because they thin with use. It is the eventual thickening that limits the time you may keep oil in your engine. The limit is both time itself (with no motor use) and/or mileage use.

A 10W-30 synthetic oil is based on a 30 weight oil. This is unlike the counterpart mineral oil based on a 10 weight oil. There is no VI improver needed. The oil is already correct for the normal operating temperature of 212 F. It has a thickness of 10 while you drive to work. It will never thin yet has the same long term problem as the mineral based oil. They both thicken with extended age.

Synthetic oils are derived in the laboratory. They are pure, usually nearly clear. I describe mineral based motor oils as a distilled, concentrated product. The impurities need to be removed from the raw petroleum. These oils are therefore less clean and contain many impurities. Oil molecules do not break down, just the additives. Generally, the synthetic oils do not have VI improvers so have less to lose.

There are some properties of synthetic oils that actually result is less wear than with mineral oils. These help increase your gas mileage as well. Due to a reduction of internal friction of the synthetic oil your engine will run a bit cooler. Wear increases as temperature increases, all other things being constant.

A main advantage that the synthetic has over the mineral based oil is the ability to lubricate at startup. Both types of oil have the same specifications at 104 F, 212 F and 302 F. It is the startup viscosity characteristics that separate these oils. Synthetic oils do not thicken as much on cooling. They have better fluidity as the temperature drops.

At temperatures below zero you will not be able to start your car with mineral oils while the synthetic oils may be used to -40 or - 50 F. Motor oil becomes permanently thicker with exposure to northerly winter type weather. This is more of a problem to mineral based oils. Waxes form. This is why it is a bad idea to even store a bottle of oil in a cold garage. It goes bad on the garage self just because it is exposed to the cold.

Since the synthetic oil thickens less on shutdown your startup will be easier and so will the stress on your engine. This is perhaps the best thing the synthetic class has over the mineral based oils.

Some people have said they use thicker oils because they only use their cars every 2, 3 or 4 weeks. They are afraid that thin oils will fall off the engine parts and result in a lack of lubrication at startup. Think about your lawn mower over the winter. I gets gummed up solid. The oil and fuel thicken over time resulting in engine failure. Anyway, oil on the surface of parts does not lubricate. It is the FLOW of oil between parts that lubricates. Thick, old, waxy oil can only be bad.

My feeling is that you can probably go 5,000 miles on the average (in a sports car) but you must change your oil in the spring time at a minimum, particularly up north. Oils form waxes in icy cold weather. There is a permanent thickening of the oil. Some automotive manufacturers are backing down on oil change intervals to 5,000 miles or less and some advocate changing the oil at least every 6 months as well. I think this is because of the tendency for oils to thicken in very hot engines (not ambient conditions, just hot engines).

I truly believe that oil is much better being too thin than too thick. As it turns out synthetic oils do cling to parts better as they have higher film strength than mineral oils. Synthetics are thinner overall. They have greater slipperiness. Yet they stick better to engine parts.

People are always asking about adding things as Slick 50 into the oil tank. Do not do this. Independent additives cannot make the oil better and in many cases makes things worse. There have been engine failures as a result of adding some of these aftermarket additives to motor oil.

Motor oil that is labeled for RACING ONLY is not usable for every day driving. Often these have more additives that are toxic to your catalytic converters and the environment. These oils generally do not have detergents.

Just about any oil brand that meets the original specifications will do.

The synthetic lubricated engine will turn over easier. This has the effect of using less power from your starter motor. It will last longer. Your battery has less of a current draw. This will also last longer. The battery was discharged less during the start so the alternator will rob less power from your engine to recharge. The alternator lasts longer and you get a little better gas economy. The only downside of synthetic lubricants is the cost. They cost 2 or 3 times as much as mineral based oils. Never-the-less I use plain Pennzoil multigrade mineral based 5W-20 in my Ford Expedition. This oil is thin enough at startup to have many of the attributes I just mentioned.

Higher revving engines need thinner oils. You do not necessarily need to go to a thicker oil while racing. Only experimentation will tell.

These same rules apply to engines of any age, loose or tight. Just because your engine is old does not mean it needs a thicker oil. It will need a thicker oil only if it is overly worn, whether new or old.

Do not go 5,000 miles with the same oil if you are racing your car. You should change the oil every 1 or 2,000 miles. If you drive your car around town then you need to change the oil for that situation. Use racing oil on the track and urban oil around town. The best situation as described by Ferrari is to use the 0W-40 around town and the 10W-60 “racing oil” on the track.

Now let me discuss what people think is a similar situation to racing. That is hot summer traffic jam driving. Your car should be able to handle this. If you have problems then you have a problem with your car, most likely in need of a cooling system overhaul. Your engine is not producing much heat at low RPM and low BHP output. The production of heat is relatively slow. It can easily be transmitted to your cooling system. The problem is that your cooling system has trouble getting rid of the heat. The oil and the coolant will slowly rise in temperature. They both rise together. The increase is no big deal for your oil. It goes to 220, then 230 F. The problem is that the cooling system can only handle heat up to 230 F. After that you overheat the cooling system and the car must be shut off. The oil never got that hot, It was just that the water got a little hotter than its system design.

These are the motor oils I recommend. …..Synthetic Class…..

60 wt:
Agip Synthetic PC 20W-50 (a thick 50 wt oil)
Redline straight 60 wt racing oil (racing only, acts as a SAE 20W-60 oil)*
Shell Helix Ultra Racing Oil 10W-60

50 wt:
Castrol Syntec 5W-50
Penn Synthetic 5W-50
Red Line 15W-50*
Shell Helix Ultra 15W-50

40 wt:
Amsoil 0W-40
Castrol European Formula 0W-30 (a thicker 30 wt oil, almost a 40 wt oil)*
Mobil One 0W-40

30 wt:
Mobil One 0W-30
Penn Synthetic 5W-30
Red Line 5W-20 (a thick 20 wt oil)*

20 wt:
Mobil One 5W-20*
Valvoline SynPower 5W-20

…..Race Oils for Street Use…..
Use these when continued sump temperatures over 240 F are expected.

60 wt:
Redline straight 60 wt racing oil (racing only, not for the street, acts as a SAE 20W-60 oil)
Shell Helix Ultra Racing Oil 10W-60
Valvoline SynPower 20W-50

50 wt:
Castrol Syntec 5W-50
Shell Helix Ultra 15W-50

40 wt:
Red Line 5W-40
Shell Helix Ultra 5W-40

30 wt:
Red Line 10W-30

20 wt:
Amsoil 5W-20
Red Line 5W-20


…..Synthetic Blends…..

60 wt:
Castrol Syntec Blend 20W-50

50 wt:
Valvoline 20W-50

40 wt:
Agip 4-Synt 10W-40
Valvoline Durablend 10W-40*

30 wt:
Castrol Syntec Blend 5W-30
Motorcraft Blend 5W-30
Valvoline Durablend 5W-30*

20 wt:
Motorcraft 5W-20*
Valvoline Durablend 5W-20

…..Non-Synthetic…..

50 wt:
None recommended - all relatively too thick at start up.

40 wt:
Penn regular Multigrade 10W-40*
Valvoline All Climate 10W-40

30 wt:
Penn regular Multigrade 5W-30*
Valvoline All Climate 5W-30

20 wt:
Penn regular Multigrade 5W-20
Mobil Clean 5000 5W-20*

If while on the road you are forced to add oil there are rules. Let us say for example that our engine has synthetic Mobil One 0W-30. Use the same type and brand if you can. If you are using Mobil 1 then it is acceptable to mix different grades but use a close grade when possible. It is not a good idea to mix say 1/2 your oil tank with 0W-30 and 1/2 with 15W-50 Mobil 1. If there is no Mobil 1 available then use the mineral based Mobil oils next,.

The last choice is to mix a synthetic of another brand. They should not react adversely if mixed but it may dilute additives. This is not a good combination. Use this combination if you must but only until an oil change can safely be performed some time soon.


Thinner oils, and specifically synthetic products are better. Some people say their engines were “designed” to run on mineral based lubricates. I have not seen anything to support this theory. The synthetic of the same viscosity as the mineral oil you are now using will be an improvement. If you go from a mineral to an even thinner synthetic you may be better off still. The pressures go up in many older engines because of this “clogging” of the arteries. Most think this is good but it is really a lessening of flow and therefore accelerates engine wear even further.

For those engines with excessive varnish and carbon buildup the engine oil additives of the detergent type may be of benefit. On the other hand you could just use a thin synthetic oil and change it every 200 miles for a while and end up with an even cleaner engine. With everything working properly you may actually need a thicker oil if that engine is overly worn. The thicker oil would be a disaster however, if the arteries were narrowed from deposits.

Remember, the only difference between a 0W-40 and a 10W-40 is that the 0W-40 thickens less after you turn off your engine. It is still too thick in the morning at startup but not as thick as the 10W-40. Yet, they are still too thick to use until they both warm up to operating temperature at which point they have the save viscosity, around 13 to 14. Remember that the 0W-30, 10W-30 and straight 30 weight oils all have a viscosity of around 10 at normal engine operating temperatures.

There is one more thing. A 20 weight oil is not half as thick as a 40 weight oil. The real scale is more like the oils having an absolute thickness of 108 and 114. Now it can be seen that the 40 weight oil is only around 10 percent thicker than the 20 weight oil. The difference is not that much at operation but at startup the difference is significant. Pressure / flow dynamics go along with this 10 percent figure. A 30 weight oil should be thought of as having an absolute viscosity of 110 and a 50 weight oil has an absolute viscosity of 120. I am talking about operating temperatures.

I thought everyone knew that 90 percent of engine wear occurs during the startup period because oil is just too thick. Some think it is good to have a thicker oil for startup since the parts shrink when cold and would otherwise “rattle.” Sure, your piston diameter will shrink on cooling but so will the diameter of your bore. The net result is about the same clearance hot and cold. This is not true for your valves. They lengthen when extremely hot. In the Murcielago they use shims instead of self adjusting valve tappets. You need to put a millimeter of clearance there so that after expansion the valve will not be held partly open when it is supposed to be closed.

If it were true that thicker oils were needed at startup then the manufacturers would not be requesting oils that thicken less on cooling. They would just specify that one should use a straight 30 or 40 weight oil. Instead, over time, they are specifying thinner and thinner oils.

The manufacturers know what parts shrink or expand and the clearance changes that result. You do not have to worry about this. If it was that easy to design engines we would all be making them.

I would like to go back to the worry that oil falls off the parts when a car is stored or sees long periods of inactivity. For the first oil change in my 575 Maranello I drained the Shell and put in 0W-30 Mobil 1. This was at 775 miles on the odometer. I drove the car home from work, put it on the lift and drained the transaxle and engine oils. I also opened and drained the oil cooler and took off every line that is in the oil system. I wanted to get every speck of the Shell oil out of there. For optimal results you are not supposed to mix synthetic oils of different brands.
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